From: owner-ammf-digest@smoe.org (alt.music.moxy-fruvous digest) To: ammf-digest@smoe.org Subject: alt.music.moxy-fruvous digest V14 #3843 Reply-To: ammf@fruvous.com Sender: owner-ammf-digest@smoe.org Errors-To: owner-ammf-digest@smoe.org Precedence: bulk alt.music.moxy-fruvous digest Friday, March 27 2020 Volume 14 : Number 3843 Today's Subjects: ----------------- How To Build Your Own SHTF Silencer At Home (100% legal) ["Build Your Own] Congratulations , You've been nominated ["Joan Riley" <*JoanRiley*@waters] Russian Date - It's Free to Review Your Matches ["RussianWomenDate" ] Your FREE bottle of probiotics is waiting to ship (address needed) ["prox] WORLDWIDE Breathing Mask Shortage: SOLVED ["Keith" Subject: How To Build Your Own SHTF Silencer At Home (100% legal) How To Build Your Own SHTF Silencer At Home (100% legal) http://heartgov.buzz/AyhCZ8-3KhsKPoGftMILyUPzZXEz8MNTz67WEQmSOKFtGMEd http://heartgov.buzz/nR4nCekDM0Rjupcfa02chBbNAIktCMAy70bi5gHxPEWvVpSF Organometallic chemistry is the study of organometallic compounds, chemical compounds containing at least one chemical bond between a carbon atom of an organic molecule and a metal, including alkaline, alkaline earth, and transition metals, and sometimes broadened to include metalloids like boron, silicon, and tin, as well. Aside from bonds to organyl fragments or molecules, bonds to 'inorganic' carbon, like carbon monoxide (metal carbonyls), cyanide, or carbide, are generally considered to be organometallic as well. Some related compounds such as transition metal hydrides and metal phosphine complexes are often included in discussions of organometallic compounds, though strictly speaking, they are not necessarily organometallic. The related but distinct term "metalorganic compound" refers to metal-containing compounds lacking direct metal-carbon bonds but which contain organic ligands. Metal ?-diketonates, alkoxides, dialkylamides, and metal phosphine complexes are representative members of this class. The field of organometallic chemistry combines aspects of traditional inorganic and organic chemistry. Organometallic compounds are widely used both stoichiometrically in research and industrial chemical reactions, as well as in the role of catalysts to increase the rates of such reactions (e.g., as in uses of homogeneous catalysis), where target molecules include polymers, pharmaceuticals, and many other types of practical products. ------------------------------ Date: Fri, 27 Mar 2020 05:09:15 -0400 From: "Joan Riley" <*JoanRiley*@watersys.guru> Subject: Congratulations , You've been nominated Congratulations , You've been nominated http://watersys.guru/H4g8dfIn-n3JqSp1Ym89Zv2YE-Y3LZL0gAXPM9_LmEggMIfv http://watersys.guru/Xx5R0WMxcM0rj-8jy7EXy1RmQjZ0F_8qPcvuNhFxh9fdwsep Unlike palladium acetate, platinum(II) acetate is not commercially available. Where a base is desired, the halides have been used in conjunction with sodium acetate. The use of platinum(II) acetylacetonate has also been reported. Several barium platinides have been synthesized in which platinum exhibits negative oxidation states ranging from ?1 to ?2. These include BaPt, Ba 3Pt 2, and Ba 2Pt. Caesium platinide, Cs 2Pt, a dark-red transparent crystalline compound has been shown to contain Pt2? anions. Platinum also exhibits negative oxidation states at surfaces reduced electrochemically. The negative oxidation states exhibited by platinum are unusual for metallic elements, and they are attributed to the relativistic stabilization of the 6s orbitals. Zeise's salt, containing an ethylene ligand, was one of the first organometallic compounds discovered. Dichloro(cycloocta-1,5-diene)platinum(II) is a commercially available olefin complex, which contains easily displaceable cod ligands ("cod" being an abbreviation of 1,5-cyclooctadiene). The cod complex and the halides are convenient starting points to platinum chemistry. Cisplatin, or cis-diamminedichloroplatinum(II) is the first of a series of square planar platinum(II)-containing chemotherapy drugs. Others include carboplatin and oxaliplatin. These compounds are capable of crosslinking DNA, and kill cells by similar pathways to alkylating chemotherapeutic agents. (Side effects of cisplatin include nausea and vomiting, hair loss, tinnitus, hearing loss, and nephrotoxicity. ------------------------------ Date: Fri, 27 Mar 2020 04:50:42 -0400 From: "RussianWomenDate" Subject: Russian Date - It's Free to Review Your Matches Russian Date - It's Free to Review Your Matches http://heartgov.buzz/_Zb3CTlykN304KCm1pxDiEzDTJdvahhUzTHwjtA0gwQKZ_QJ http://heartgov.buzz/0K3EM7CUF2TDr7zCs60p8y3pY75nyCdWeaYzqHNdmDzyX1rt Platinum is an extremely rare metal, occurring at a concentration of only 0.005 ppm in Earth's crust. It is sometimes mistaken for silver. Platinum is often found chemically uncombined as native platinum and as alloy with the other platinum-group metals and iron mostly. Most often the native platinum is found in secondary deposits in alluvial deposits. The alluvial deposits used by pre-Columbian people in the ChocC3 Department, Colombia are still a source for platinum-group metals. Another large alluvial deposit is in the Ural Mountains, Russia, and it is still mined. In nickel and copper deposits, platinum-group metals occur as sulfides (e.g. (Pt,Pd)S), tellurides (e.g. PtBiTe), antimonides (PdSb), and arsenides (e.g. PtAs2), and as end alloys with nickel or copper. Platinum arsenide, sperrylite (PtAs2), is a major source of platinum associated with nickel ores in the Sudbury Basin deposit in Ontario, Canada. At Platinum, Alaska, about 17,000 kg (550,000 ozt) was mined between 1927 and 1975. The mine ceased operations in 1990. The rare sulfide mineral cooperite, (Pt,Pd,Ni)S, contains platinum along with palladium and nickel. Cooperite occurs in the Merensky Reef within the Bushveld complex, Gauteng, South Africa. In 1865, chromites were identified in the Bushveld region of South Africa, followed by the discovery of platinum in 1906. In 1924, the geologist Hans Merensky discovered a large supply of platinum in the Bushveld Igneous Complex in South Africa. The specific layer he found, named the Merensky Reef, contains around 75% of the world's known platinum. The large copperbnickel deposits near Norilsk in Russia, and the Sudbury Basin, Canada, are the two other large deposits. In the Sudbury Basin, the huge quantities of nickel ore processed make up for the fact platinum is present as only 0.5 ppm in the ore. Smaller reserves can be found in the United States, for example in the Absaroka Range in Montana. In 2010, South Africa was the top producer of platinum, with an almost 77% share, followed by Russia at 13%; world production in 2010 was 192,000 kg (423,000 lb). Large platinum deposits are present in the state of Tamil Nadu, India. Platinum exists in higher abundances on the Moon and in meteorites. Correspondingly, platinum is found in slightly higher abundances at sites of bolide impact on Earth that are associated with resulting post-impact volcanism, and can be mined economically; the Sudbury Basin is one such ex ------------------------------ Date: Fri, 27 Mar 2020 06:16:23 -0400 From: "Survival" Subject: Your new favorite "Gun Toy" Your new favorite "Gun Toy" http://instahards.us/ajg1RuBDDh7XFVOPHeJN03CTs0ZbkFxoh7s04Rmcdnc7bWsM http://instahards.us/8ejf01I7w597lS5HFmt4xjU5Ou5Ya-rYUc5wWxQVUDitzM2J Many complexes feature coordination bonds between a metal and organic ligands. The organic ligands often bind the metal through a heteroatom such as oxygen or nitrogen, in which case such compounds are considered coordination compounds. However, if any of the ligands form a direct M-C bond, then complex is considered to be organometallic. The IUPAC explicitly includes transition metals, main group metals, and semimetals, such as boron, silicon, arsenic and selenium as examples of the central metal M. Although the IUPAC has not formally defined the term, some chemists use the term "metalorganic" to describe any compound containing an organic ligand regardless of the presence of a direct M-C bond. A naturally occurring transition metal alkyl complex is methylcobalamin (a form of Vitamin B12), with a cobalt-methyl bond. This subset of complexes is often discussed within the subfield of bioorganometallic chemistry. Illustrative of the many functions of the B12-dependent enzymes, the MTR enzyme catalyzes the transfer of a methyl group from a nitrogen on N5-methyl-tetrahydrofolate to the sulfur of homocysteine to produce methionine. The status of compounds in which the canonical anion has a delocalized structure in which the negative charge is shared with an atom more electronegative than carbon, as in enolates, may vary with the nature of the anionic moiety, the metal ion, and possibly the medium; in the absence of direct structural evidence for a carbonbmetal bond, such compounds are not considered to be organometallic. For instance, lithium enolates often contain only Li-O bonds and are not organometallic, while zinc enolates (Reformatsky reagents) contain both Zn-O and Zn-C bonds, and are organometallic in nature. ------------------------------ Date: Fri, 27 Mar 2020 03:41:49 -0400 From: "prox10" Subject: Your FREE bottle of probiotics is waiting to ship (address needed) Your FREE bottle of probiotics is waiting to ship (address needed) http://heartgov.buzz/aUp2-JT3ahM4aU0IWesf1bJrZwxwqJqIbJaZEDbHSBSzuYk http://heartgov.buzz/_mVZYPTl-2-3oSJiPn_Mf_UG2UrYHgTiA0JZacI2zvEumA On 20 May 1875 an international treaty known as the Convention du MC(tre (Metre Convention) was signed by 17 states. This treaty established an international organisation, the Bureau international des poids et mesures (BIPM), consisting of: ConfC)rence gC)nC)rale des poids et mesures (CGPM), an intergovernmental conference of official delegates of member nations and the supreme authority for all actions; ComitC) international des poids et mesures (CIPM), consisting of selected scientists and metrologists, which prepares and executes the decisions of the CGPM and is responsible for the supervision of the International Bureau of Weights and Measures; a permanent laboratory and secretariat function, the activities of which include the establishment of the basic standards and scales of the principal physical quantities and maintenance of the international prototype standards. The CGPM acts on behalf of the governments of its members. In so doing, it appoints members to the CIPM, receives reports from the CIPM which it passes on to the governments and national laboratories on member states, examines and where appropriate approves proposals from the CIPM in respect of changes to the International System of Units (SI), approves the budget for the BIPM (over b,13 million in 2018) and it decides all major issues concerning the organization and development of the BIPM. The structure is analogous to that of a stock corporation. The BIPM is the organisation, the CGPM is the general meeting of the shareholders, the CIPM is the board of directors appointed by the CGPM, and the staff at the site in Saint-Cloud perform the day-to-day work. Membership criteria The CGPM recognises two classes of membership b full membership for those states that wish to participate in the activities of the BIPM and associate membership for those countries or economies[Note 1] that only wish to participate in the CIPM MRA program. Associate members have observer status at the CGPM. Since all formal liaison between the convention organisations and national governments is handled by the member state's ambassador to France,[Note 2] it is implicit that member s ------------------------------ Date: Thu, 26 Mar 2020 04:54:21 -0400 From: "Keith" Subject: WORLDWIDE Breathing Mask Shortage: SOLVED WORLDWIDE Breathing Mask Shortage: SOLVED http://stopsqribble.bid/EZyiVrI8deBEW-gvZmrRjoLq3QfVTo4J15Dss0T_EqJPbasB http://stopsqribble.bid/zbXw1pLge-_Gmq9noG7IDOYzehZh6eWILYUP0mEvP8_BzII The minimum safe lower limit for the partial pressures of oxygen in a gas mixture is 0.16 bars (16 kPa) absolute. Hypoxia and sudden unconsciousness becomes a problem with an oxygen partial pressure of less than 0.16 bar absolute. Oxygen toxicity, involving convulsions, becomes a problem when oxygen partial pressure is too high. The NOAA Diving Manual recommends a maximum single exposure of 45 minutes at 1.6 bar absolute, of 120 minutes at 1.5 bar absolute, of 150 minutes at 1.4 bar absolute, of 180 minutes at 1.3 bar absolute and of 210 minutes at 1.2 bar absolute. Oxygen toxicity becomes a risk when these oxygen partial pressures and exposures are exceeded. The partial pressure of oxygen determines the maximum operating depth of a gas mixture. Narcosis is a problem when breathing gases at high pressure. Typically, the maximum total partial pressure of narcotic gases used when planning for technical diving may be around 4.5 bar absolute, based on an equivalent narcotic depth of 35 metres (115 ft). The effect of a toxic contaminant such as carbon monoxide in breathing gas is also related to the partial pressure when breathed. A mixture which may be relatively safe at the surface could be dangerously toxic at the maximum depth of a dive, or a tolerable level of carbon dioxide in the breathing loop of a diving rebreather may become intolerable within seconds during descent when the partial pressure rapidly increases, and could lead to panic or incapacitation of the diver. ------------------------------ Date: Thu, 26 Mar 2020 05:53:21 -0400 From: "Germidin" Subject: Germidin - Alcohol Disinfection Cleaning Wipes Germidin - Alcohol Disinfection Cleaning Wipes http://tvmiracle.buzz/W8Q1X18z1v2jhhZ6abTUo3h0A_-IBVMBn7tF0UM7P66p37q4 http://tvmiracle.buzz/XDlzRwuX56GDf19V_m4jIBOGEYk2jDtrIDk9oPUjWmC5Wprq Carbon dioxide (chemical formula CO 2) is a colorless gas with a density about 60% higher than that of dry air. Carbon dioxide consists of a carbon atom covalently double bonded to two oxygen atoms. It occurs naturally in Earth's atmosphere as a trace gas. The current concentration is about 0.04% (412 ppm) by volume, having risen from pre-industrial levels of 280 ppm. Natural sources include volcanoes, hot springs and geysers, and it is freed from carbonate rocks by dissolution in water and acids. Because carbon dioxide is soluble in water, it occurs naturally in groundwater, rivers and lakes, ice caps, glaciers and seawater. It is present in deposits of petroleum and natural gas. Carbon dioxide is odorless at normally encountered concentrations, but at high concentrations, it has a sharp and acidic odor. At such concentrations it generates the taste of soda water in the mouth. As the source of available carbon in the carbon cycle, atmospheric carbon dioxide is the primary carbon source for life on Earth and its concentration in Earth's pre-industrial atmosphere since late in the Precambrian has been regulated by photosynthetic organisms and geological phenomena. Plants, algae and cyanobacteria use light energy to photosynthesize carbohydrate from carbon dioxide and water, with oxygen produced as a waste product. CO 2 is produced by all aerobic organisms when they metabolize carbohydrates and lipids to produce energy by respiration. It is returned to water via the gills of fish and to the air via the lungs of air-breathing land animals, including humans. Carbon dioxide is produced during the processes of decay of organic materials and the fermentation of sugars in bread, beer and wine making. It is produced by combustion of wood and other organic materials and fossil fuels such as coal, peat, petroleum and natural gas. It is an unwanted byproduct in many large scale oxidation processes, for example, in the production of acrylic acid (over 5 million tons/year). It is a versatile industrial material, used, for example, as an inert gas in welding and fire extinguishers, as a pressurizing gas in air guns and oil recovery, as a chemical feedstock and as a supercritical fluid solvent in decaffeination of coffee and supercritical drying. It is added to drinking water and carbonated beverages including beer and sparkling wine to add effervescence. The frozen solid form of CO 2, known as dry ice is used as a refrigerant and as an abrasive in dry-ice blasting. It is a feedstock for the synthesis of fuels and chemical ------------------------------ Date: Wed, 25 Mar 2020 09:24:38 -0400 From: "Pure Herbal Total Defense" Subject: ORDER PENDING: Immunity Boost Blend ORDER PENDING: Immunity Boost Blend http://resurge.guru/gEKB6VxQETQ31cwox71UwMalavvdpctOsco6sDl4bPNZ3evC http://resurge.guru/uvOhbF463I0IjpXDGYkMarVNjJoBlwlsPtZUqs5X6PqJnuI The study of application of transgenes is a rapidly growing area of molecular biology. In fact, it is predicted that in the next two decades, 300,000 lines of transgenic mice will be generated. Researchers have identified many applications for transgenes, particularly in the medical field. Scientists are focusing on the use of transgenes to study the function of the human genome in order to better understand disease, adapting animal organs for transplantation into humans, and the production of pharmaceutical products such as insulin, growth hormone, and blood anti-clotting factors from the milk of transgenic cows.[citation needed] There are currently five thousand known genetic diseases, and the potential to treat these diseases using transgenic animals is, perhaps, one of the most promising applications of transgenes. There is a potential to use human gene therapy to replace a mutated gene with an unmutated copy of a transgene in order to treat the genetic disorder. This can be done through the use of Cre-Lox or knockout. Moreover, genetic disorders are being studied through the use of transgenic mice, pigs, rabbits, and rats. More recently, scientists have also begun using transgenic goats to study genetic disorders related to fertility. Transgenes may soon be used for xenotransplantation from pig organs. Through the study of xeno-organ rejection, it was found that an acute rejection of the transplanted organ occurs upon the organ's contact with blood from the recipient due to the recognition of foreign antibodies on endothelial cells of the transplanted organ. Scientists have identified the antigen in pigs that causes this reaction, and therefore are able to transplant the organ without immediate rejection by removal of the antigen. However, the antigen begins to be expressed later on, and rejection occurs. Therefore, further research is being conducted.[citation needed] Transgenes are being used by manufactures to produce goods such as milk with high levels of proteins, silk from the milk of goats, and microorganisms that are capable of producing proteins that contain enzymes that increase the rate of industrial reactions. Agricultural applications aim to selectively breed animals for particular traits and animals that are resistant to diseases ------------------------------ End of alt.music.moxy-fruvous digest V14 #3843 **********************************************